Cristin Milioti and Ben Feldman Talk ‘A to Z’ Chemistry

Cristin Milioti (How I Met Your Mother) and Ben Feldman (Mad Men) play apparently mismatched couples in the upcoming NBC comedy A to Z. The series premiers October 2 (9:30 pm et/pt), but the pilot can currently be viewed on the show’s official page.

Milioti’s chemistry with Josh Radnor led many How I Met Your Mother fans to wonder why Ted and the mom didn’t live happily ever after. For Feldman, his inevitably heartbreaking and memorable run as Michael Ginsberg was anchored by his creative rapport with co-star Elisabeth Moss.

During the A to Z interviews, I asked Milioti and Feldman if chemistry among actors is simply innate or if it can be worked on through the rehearsal process. Check out the video below for their answer.